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FileThe dimeric structure of the (Ca2+)8(PO4)2 cluster. The (Ca(2+))8(PO(4))(2) cluster has been determined by X-ray diffraction in a = 9.6347(6), c = 12.5317(8) A and Z = 4. Single crystals of Ca(8)(PO(4))(4)Cl(2)O(2)·H(2)O were grown from a mixture of CaCl(2), NH(4)H(2)PO(4), and H(2)O and were characterized by X-ray diffraction methods. The crystal structure shows a distorted cage structure with two independent Ca(4) clusters. In the larger unit cell Ca(4) atoms are coordinated to six PO(4) tetrahedra and the PO(4) tetrahedra are in turn bridged to a central PO(4) tetrahedron by one Cl. The other Ca(4) cluster is embedded in the Ca(4) cluster and is not accessible to solvent. The O-Ca-O angle (between the two PO(4) tetrahedra) is larger than in the (Ca(2+))(8)(PO(4))(2) cluster in spite of the presence of only one PO(4) tetrahedron in the central Ca(4) cluster of the (Ca(2+))(8)(PO(4))(2) cluster. The crystal structure of Ca(8)(PO(4))(4)Cl(2)O(2)·H(2)O resembles that of the (Ca(2+))(8)(PO(4))(2) cluster (a = 9.7402(8), c = 11.5372(5) A, Z = 4) and differs only in the arrangement of the PO(4) tetrahedra relative to the Ca(4) cluster.The only major new addition to the roster since the beginning of the season is Chelsea's Cesc Fabregas. The midfielder has replaced Juan Mata as the team's playmaker and he is expected to take over a lot of his former captain's duties. The other major change is the departure of manager Jose Mourinho, and so far he has been replaced by Guus Hiddink, the coach of Dutch national side. The first game will be against newly

 

 

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